Material State Data Sheet
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
- Product Name: PVultex Prevulcanised Natural Rubber Latex - Regular Grades
- Synonyms: PVL; PVM; PVH; PVML; PVM 9001; PVH 9002; PVMX; PVMZ; PVL 8016; PVH 7001;
PVH 7003; PSH
1.2 Relevant identified uses of the substance or mixture and uses advised against
- Use of the substance/mixture: Dipped Articles, Latex Foam, Adhesive, Coating, Medical Devices,
Prophylactics, Binder, Rubber compounds, Art and hobbies
- Use advised against: None
1.3 Details of the supplier of the safety data sheet
- Name of Supplier:
Liquid Latex Direct Ltd
- Address of Supplier: Kingsferry House, Stather Road, Burton Upon Stather, Lincolnshire, DN15 9DJ, U.K.
- Telephone:
+44 7702245248
- Fax: n/a
- Responsible Person: martin@kingsferrywharf.com
- Email: martin@kingsferrywharf.com
1.4 Emergency telephone number
- Emergency Telephone: +44 7702245248 available from 9:00 to 18:00 hours (GMT)
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
- CLP: This product is not classified as hazardous according to directive 1272/2008.
- This product does not meet the criteria for classification in any hazard class according to Regulation (EC)
No 1272/2008 on classification, labelling and packaging of substances and mixtures. However a safety
data sheet is being supplied for it upon request as it contains a substance for which there is a Union
Workplace exposure limit
2.2 Label elements
- Signal Word: None assigned
- Low hazard expected under normal conditions of use
Hazard statements
None
Precautionary statements
Wash hands and working surfaces thoroughly after handling.
2.3 Other hazards
- Harmful to aquatic life if allowed to enter public drains, sewers and watercourses
- Contains Zinc bis(dibutylditthiocarbamate). May produce an allergic reaction.
SECTION 3: Composition/information on ingredients
3.2 Mixtures:
Total solid content of 61.5% (minimum),
Dry rubber content of 60% (minimum),
Volatile fatty acid, copper, manganese content of 1.5% (maximum)
SECTION 4: First aid measures
4.1 General
- When in doubt or symptoms persist, seek medical attention
4.2 Contact with skin
- After contact with skin, take off immediately all contaminated clothing, and wash immediately with plenty of soap and water
- Seek medical attention if irritation persists
4.3 Contact with eyes
- If substance has got into eyes, immediately wash out with plenty of water for at least 15 minutes
- May cause redness and irritation
- Seek medical attention if irritation persists
4.4 Inhalation
- Ammonia present, may cause respiratory difficulties in poorly ventilated environments.
- If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
4.5 Ingestion
- If swallowed, rinse mouth with water (only if the person is conscious)
- Do not induce vomiting because of risk of aspiration into the lungs. If aspiration is suspected obtain
immediate medical attention
- Seek medical attention if ill effects occur
4.6 Most important symptoms and effects, both acute and delayed
- Possible redness and irritation of affected areas
4.7 Indication of any immediate medical attention and special treatment needed
SECTION 5: Firefighting measures
5.1 Extinguishing media
- Not flammable. In case of fire use extinguishing media appropriate to surrounding conditions
5.2 Special hazards arising from the substance or mixture
- Smoke from fires is corrosive. Take precautions to protect personnel from exposure
5.3 Advice for firefighters
- Fight fire with normal precautions from a reasonable distance.
- Prevent run off water from entering drains if possible
- Smoke from fires is corrosive. Take precautions to protect personnel from exposure
SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
- Contain spillage by any means possible
- Wear eye/face protection
- Wear protective clothing as per section 8
6.2 Environmental precautions
- Contain spillage by any means possible
- Do not allow to enter public sewers and watercourses
- If polluted water reaches drainage systems or water courses, immediately inform appropriate authorities
6.3 Methods and material for containment and cleaning up
- Absorb spillage in inert material and shovel up
- Remove contaminated material to safe location for subsequent disposal
6.4 Reference to other sections
- See Section 7 for information on safe handling
- See Section 8 for information on personal protective equipment
- See Section 13 for information on disposal
SECTION 7: Handling and storage
7.1 Precautions for safe handling
- The usual precautions for handling chemicals should be observed
- Use only in well ventilated areas
- Wear protective gloves/protective clothing/eye protection/face protection.
- If skin irritation or rash occurs: Get medical advice/attention.
7.2 Conditions for safe storage, including any incompatibilities
- Keep only in the original container in a cool, well ventilated place away from frost
- Keep in containers made of material similar to the original
7.3 Specific end use(s)
- Not applicable
SECTION 8: Exposure controls/personal protection
8.1 Control parameters
- No exposure limits have been set for this substance
Substances
8.2 Exposure controls
- Ammonia present, may cause respiratory difficulties in poorly ventilated environments.
- In case of insufficient ventilation, wear suitable respiratory equipment
- Wear suitable protective clothing, including eye/face protection and gloves (disposable are recommended)
Gloves
Goggles
Suit
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
- Physical state: liquid
- Colour: white
- Odour: Ammonia odour
- Melting point/Range: not applicable
- Freezing point: 0 °C to 5 °C at 1000 mm/Hg
- Boiling Point/Range: 99 °C to 101 °C at 1000 mm /Hg
- Flash point - not applicable
- Flammability: Non-flammable
- pH: >9.0
- Solubility in water: Emulsifies in water
- Density: 0.94 - 0.96 g/cm³ at 20 °C
- Auto-ignition point - not applicable
- Viscosity: <150 mPa.s at 25 °C
9.2 Other information
- None
SECTION 10: Stability and reactivity
10.1 Reactivity
- No hazardous reactions known if used for its intended purpose
10.2 Chemical stability
- Stable
10.3 Possibility of hazardous reactions
- No hazardous reactions known if used for its intended purpose
10.4 Conditions to avoid
- Avoid extreme temperature, frost and direct sunlight.
10.5 Incompatible materials
- Incompatible with acid
- Incompatible with strong oxidizing substances
10.6 Hazardous decomposition products
- No hazardous decomposition products known
SECTION 11: Toxicological information
11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008
Acute toxicity
Estimated LD₅₀ (oral) (ATE) : >2000 mg/kg
Estimated LD₅₀ (dermal) (ATE) : >4000 mg/kg
Estimated LD₅₀ (inhalational) (ATE) : >20 mg/l/4hr (gas/vapour)
zinc oxide
LD₅₀ (oral, rat): >5000 mg/kg
LC₅₀ (inhalation) : >5700 mg/l/4h LD₅₀ (dermal) : >2000 mg/kg
zinc bis(dibutyldithiocarbamate)
LD₅₀ (oral, rat): >5000 mg/kg LD₅₀ (dermal, rabbit): >2000 mg/kg
Skin corrosion/irritation
May cause redness and irritation
Serious eye damage/irritation
May cause redness and irritation
Respiratory or skin sensitisation
In cases of severe exposure, asthma may develop In cases of severe exposure, dermatitis may develop
Germ cell mutagenicity
Based on the available data, the classification criteria are not met
Carcinogenicity
Based on the available data, the classification criteria are not met
Reproductive toxicity
Based on the available data, the classification criteria are not met
STOT (specific target organ toxicity) - single exposure
Based on the available data, the classification criteria are not met
STOT (specific target organ toxicity) - repeated exposure
Based on the available data, the classification criteria are not met
Aspiration hazard
Based on the available data, the classification criteria are not met 11.2 Information on other hazards
- No information available
12. ECOLOGICAL INFORMATION
12.1 Toxicity: The product is not hazardous to the environment.
12.2 Persistence and degradability: Not relevant.
12.3 Bio accumulative potential: Not relevant.
12.4 Mobility in soil: Not relevant.
12.5 Results of PBT and vPvB assessment: Not relevant as Liquid Latex 60% is not identified as a PBT substance.
12.6 Other adverse effects: Not relevant.
SECTION 13: Disposal considerations
13.1 Classification
- No special precautions are required for this product
13.2 Waste treatment methods
- See Section 6.3
- Disposal should be in accordance with local, state or national legislation
- Incineration by an approved method could be considered
- Do not allow to enter public sewers and watercourses
SECTION 14: Transport information
Not classified as hazardous for transport
14.1 UN number or ID number
- UN No.: Not applicable
14.2 UN proper shipping name
- Proper Shipping Name: Not applicable
14.3 Transport hazard class(es)
- Hazard Class: Not applicable
14.4 Packing group
- Packing Group: Not applicable
14.5 Environmental hazards
- Not classified
14.6 Special precautions for user
- Not classified
14.7 Maritime transport in bulk according to IMO instruments
- Not applicable
1SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Substances
- This substance or mixture is not classified under CLP and does not legally require a SDS. This document
is therefore issued for information and guidance purposes only.
15.2 Chemical safety assessment
- A chemical safety assessment is not required under REACH
SECTION 16:
Other information
Text not given with phrase codes where they are used elsewhere in this safety data sheet:- H302: Harmful if swallowed. H314: Causes severe skin burns and eye damage. H315: Causes skin irritation. H317: May cause an allergic skin reaction. H332: Harmful if inhaled. H335: May cause respiratory irritation. H400: Very toxic to aquatic life. H410: Very toxic to aquatic life with long lasting effects.
This Safety Data Sheet is provided in compliance with the EC Regulations 1907/2006, 1272/2008, 2015/830 and 2020/878
Goggles
Suit
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
- Physical state: liquid
- Colour: white
- Odour: Ammonia odour
- Melting point/Range: not applicable
- Freezing point: 0 °C to 5 °C at 1000 mm/Hg
- Boiling Point/Range: 99 °C to 101 °C at 1000 mm /Hg
- Flash point - not applicable
- Flammability: Non-flammable
- pH: >9.0
- Solubility in water: Emulsifies in water
- Density: 0.94 - 0.96 g/cm³ at 20 °C
- Auto-ignition point - not applicable
- Viscosity: <150 mPa.s at 25 °C
9.2 Other information
- None
SECTION 10: Stability and reactivity
10.1 Reactivity
- No hazardous reactions known if used for its intended purpose
10.2 Chemical stability
- Stable
10.3 Possibility of hazardous reactions
- No hazardous reactions known if used for its intended purpose
10.4 Conditions to avoid
- Avoid extreme temperature, frost and direct sunlight.
10.5 Incompatible materials
- Incompatible with acid
- Incompatible with strong oxidizing substances
10.6 Hazardous decomposition products
- No hazardous decomposition products known
SECTION 11: Toxicological information
11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008
Acute toxicity
Estimated LD₅₀ (oral) (ATE) : >2000 mg/kg
Estimated LD₅₀ (dermal) (ATE) : >4000 mg/kg
Estimated LD₅₀ (inhalational) (ATE) : >20 mg/l/4hr (gas/vapour)
zinc oxide
LD₅₀ (oral, rat): >5000 mg/kg
LC₅₀ (inhalation) : >5700 mg/l/4h LD₅₀ (dermal) : >2000 mg/kg
zinc bis(dibutyldithiocarbamate)
LD₅₀ (oral, rat): >5000 mg/kg LD₅₀ (dermal, rabbit): >2000 mg/kg
Skin corrosion/irritation
May cause redness and irritation
Serious eye damage/irritation
May cause redness and irritation
Respiratory or skin sensitisation
In cases of severe exposure, asthma may develop In cases of severe exposure, dermatitis may develop
Germ cell mutagenicity
Based on the available data, the classification criteria are not met
Carcinogenicity
Based on the available data, the classification criteria are not met
Reproductive toxicity
Based on the available data, the classification criteria are not met
STOT (specific target organ toxicity) - single exposure
Based on the available data, the classification criteria are not met
STOT (specific target organ toxicity) - repeated exposure
Based on the available data, the classification criteria are not met
Aspiration hazard
Based on the available data, the classification criteria are not met 11.2 Information on other hazards
- No information available
12. ECOLOGICAL INFORMATION
12.1 Toxicity: The product is not hazardous to the environment.
12.2 Persistence and degradability: Not relevant.
12.3 Bio accumulative potential: Not relevant.
12.4 Mobility in soil: Not relevant.
12.5 Results of PBT and vPvB assessment: Not relevant as Liquid Latex 60% is not identified as a PBT substance.
12.6 Other adverse effects: Not relevant.
SECTION 13: Disposal considerations
13.1 Classification
- No special precautions are required for this product
13.2 Waste treatment methods
- See Section 6.3
- Disposal should be in accordance with local, state or national legislation
- Incineration by an approved method could be considered
- Do not allow to enter public sewers and watercourses
SECTION 14: Transport information
Not classified as hazardous for transport
14.1 UN number or ID number
- UN No.: Not applicable
14.2 UN proper shipping name
- Proper Shipping Name: Not applicable
14.3 Transport hazard class(es)
- Hazard Class: Not applicable
14.4 Packing group
- Packing Group: Not applicable
14.5 Environmental hazards
- Not classified
14.6 Special precautions for user
- Not classified
14.7 Maritime transport in bulk according to IMO instruments
- Not applicable
1SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Substances
- This substance or mixture is not classified under CLP and does not legally require a SDS. This document
is therefore issued for information and guidance purposes only.
15.2 Chemical safety assessment
- A chemical safety assessment is not required under REACH
SECTION 16:
Other information
Text not given with phrase codes where they are used elsewhere in this safety data sheet:- H302: Harmful if swallowed. H314: Causes severe skin burns and eye damage. H315: Causes skin irritation. H317: May cause an allergic skin reaction. H332: Harmful if inhaled. H335: May cause respiratory irritation. H400: Very toxic to aquatic life. H410: Very toxic to aquatic life with long lasting effects.
This Safety Data Sheet is provided in compliance with the EC Regulations 1907/2006, 1272/2008, 2015/830 and 2020/878